4.7 Article

Dynamic covalent templated-synthesis of [c2] daisy chains

Journal

CHEMICAL COMMUNICATIONS
Volume 48, Issue 84, Pages 10401-10403

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c2cc35522a

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Funding

  1. Non-Equilibrium Energy Research Center which is an Energy Frontier Research Center
  2. US. Department of Energy, Offices of Basic Energy Sciences [DE-SC0000989]

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A couple of [c2] daisy chains have been assembled in each case from four components in quantitative yields at room temperature in acetonitrile as a result of the self-templated clippings of their [24]crown-8 rings by reversible imine bond formation around secondary dialkylammonium recognition sites in their stalks.

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