Journal
CHEMICAL COMMUNICATIONS
Volume 48, Issue 80, Pages 10052-10054Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c2cc34800d
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Funding
- National Science Foundation of China [21172092, 20972057]
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A novel and efficient synthesis of 2-bromo(chloro)-3-selenyl(sulfenyl)-indoles through tandem reactions of 2-(gem-dibromo(chloro)vinyl)-N- methylsulfonylanilines with diselenides and disulfides in the presence of t-BuOLi and I-2 (10 mol%) in DMSO was developed. The reactions generated the desired products in good yields with high regio-selectivity under transition-metal-free conditions in one-pot.
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