4.7 Article

Directional stack exchange along oriented oligothiophene stacks

Journal

CHEMICAL COMMUNICATIONS
Volume 48, Issue 86, Pages 10618-10620

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c2cc35773a

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Funding

  1. University of Geneva
  2. European Research Council (ERC Advanced Investigator)
  3. National Centre of Competence in Research (NCCR) Chemical Biology
  4. Swiss NSF
  5. Curie Fellowship

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Directional growth of pi-basic oligothiophene stacks on solid substrates is achieved by self-organizing, surface-initiated disulfide exchange polymerization. Successful addition of co-axial pi-acidic stacks by templated hydrazone exchange provides general access to multicomponent architectures of unique complexity.

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