Journal
CHEMICAL COMMUNICATIONS
Volume 48, Issue 84, Pages 10410-10412Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c2cc35777a
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- German Science Foundation (DFG)
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Mono- and diplatinum plumbylene complexes are prepared in which the bonding comprises synergic sigma donation between the Pt and Pb atoms. The bonding distinguishes the complexes from both the classical Fischer carbene bonding model and M > Pb dative-only bonding. The Pt-Pb bond of the monoplatinum complex is stable, while the diplatinum complex reversibly loses one Pt fragment.
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