Journal
CHEMICAL COMMUNICATIONS
Volume 48, Issue 80, Pages 10040-10042Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c2cc34136k
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Funding
- Science Foundation Ireland (SFI) [RFP/08/CHE1251, 09/IN.1/B2627]
- University College Dublin
- Stanford University
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Sequential treatment of racemic phosphine oxides with oxalyl chloride and chiral non-racemic alcohol generates the same ratios of diastereomeric alkoxyphosphonium salts obtained in the corresponding asymmetric Appel process, strongly implicating the intermediate chlorophosphonium salt in the stereoselecting step. Subsequent reduction allows a novel synthesis of enantio-enriched P-stereogenic phosphines-phosphine boranes.
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