Journal
CHEMICAL COMMUNICATIONS
Volume 48, Issue 33, Pages 3954-3956Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c2cc30394a
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Funding
- Spanish Ministry of Science and Innovation [CTQ2010-15833, CSD2007-00006]
- Junta de Andalucia [FQM-119, P09-FQM-5117]
- Spanish Ministry of Education [AP-4193]
- U. S. National Science Foundation [CHE-0948417]
- Direct For Mathematical & Physical Scien [948417] Funding Source: National Science Foundation
- Division Of Chemistry [948417] Funding Source: National Science Foundation
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New quadruply bonded dimolybdenum complexes of the terphenyl ligand Ar-Xyl2 (Ar-Xyl2 = C6H3-2,6-(C6H3-2,6-Me-2)(2)) have been prepared and structurally characterized. The steric hindrance exerted by the Ar-Xyl2 groups causes the Mo atoms to feature unsaturated four-coordinate structures and a formal fourteen-electron count.
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