Journal
CHEMICAL COMMUNICATIONS
Volume 48, Issue 54, Pages 6779-6781Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c2cc32270f
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Funding
- Spain's MICINN [MAT2010-14902, MAT2010-20843-C02-01, MAT2009-06200-E/MAT, FIS2007-61114, MAT2009-13488, CSD2007-00010, CSD2010-00024]
- CAM [S2009/MAT-1467, S2009/MAT-1726, CCG10-UAM/MAT-5881]
- EU [MALL PITN-GA-2009-23884]
- Brazilian Agencies CNPq
- FAPEMIG
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The reaction between 1,3,5-tris(4-hydroxyphenyl)benzene and benzene-1,3,5-tricarbonyl trichloride leads to polyester condensation and formation of a novel COF on an Au(111) surface. The characterization performed in situ by means of variable temperature STM and XPS reveals the formation of an array of hexagonal cavities with ca. 2 nm size.
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