☆ 4.7 Article

A robust zirconium N-heterocyclic carbene complex for the living and highly stereoselective ring-opening polymerization of rac-lactide

CHEMICAL COMMUNICATIONS (2012)

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Journal

CHEMICAL COMMUNICATIONS
Volume 48, Issue 16, Pages 2213-2215

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c2cc16819g

Keywords

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Categories

Chemistry, Multidisciplinary

Funding

  1. CNRS
  2. University of Strasbourg
  3. Clariant (Switzerland)

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A readily accessible and robust Zr-NHC complex was found to polymerize rac-lactide in a highly controlled, living and stereoselective manner to afford heterotactic PLA.

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