4.7 Article

Re2O7-catalyzed three-component synthesis of protected secondary and tertiary homoallylic amines

Journal

CHEMICAL COMMUNICATIONS
Volume 48, Issue 12, Pages 1820-1822

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c2cc15472b

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Funding

  1. DST, India
  2. CSIR, New Delhi

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Three-component synthesis of protected secondary and for the first time'' tertiary homoallylic amines is achieved from carbonyl, carbamate, and allyltrimethylsilanes using a Re2O7-catalyst under mild and open flask conditions. Excellent chemoselectivities and diastereoselectivities were observed.

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