4.7 Article

Complex clover cross-sectioned nanotubules exist in the structure of the first uranium borate phosphate

Journal

CHEMICAL COMMUNICATIONS
Volume 48, Issue 29, Pages 2334-2336

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c2cc17517g

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Funding

  1. Deutsche Forschungsgemeinschaft [DE 412/43-1]
  2. Chemical Sciences, Geosciences, and Biosciences Division, Office of Basic Energy Sciences, Office of Science, U.S. Department of Energy [DE-SC0002215]

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An actinide borate phosphate was prepared via a high temperature solid-state reaction. This phase exhibits unprecedented complex inorganic nanotubular fragments with an external diameter of similar to 2 x 2 nm. The nanotubular aggregates are based on borate tubes where the exterior of the tubes is decorated with UO2(PO4)(3) moieties to form a complex shape with a cross-section similar to the clover cross.

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