Journal
CHEMICAL COMMUNICATIONS
Volume 48, Issue 21, Pages 2707-2709Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c2cc17731e
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- DFG
- University of Siegen
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Iridium complex [(pq)(2)IrCl](2) (1) is established as a quantitatively operating lab-on-a-molecule in aqueous media at physiological pH. Acting as a chemodosimeter, 1 uses two channels, PL and ECL, for the detection of cyanide and acetate, with the former undergoing nucleophilic attack and the latter Kolbe electrolysis and radical-metal combination.
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