4.7 Article

Palladium-catalyzed asymmetric addition of diarylphosphines to N-tosylimines

Journal

CHEMICAL COMMUNICATIONS
Volume 48, Issue 90, Pages 11148-11150

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c2cc35563a

Keywords

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Funding

  1. NSFC [20902099, 21172238]
  2. National Basic Research Program of China (973 Program) [2010CB833300]
  3. SIOC

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Bis(phosphine) pincer-Pd complex-catalyzed asymmetric addition of diarylphosphines to N-tosylimines was developed for the synthesis of chiral phosphine sulfides with high stereoselectivities (up to 96% ee) under mild conditions.

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