Journal
CHEMICAL COMMUNICATIONS
Volume 48, Issue 11, Pages 1653-1655Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c2cc16821a
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- Ministry of Education, Culture, Sports, Science, and Technology of Japan [21350036]
- Japan Society for the Promotion of Science for Young Scientist
- Grants-in-Aid for Scientific Research [09J05859, 21350036, 22108527] Funding Source: KAKEN
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The Mo-based polyoxometalates containing mono-and dicobalt(III) catalyst cores, [CoMo6O24H6](3-) and [Co2Mo10O38H4](6-), were found to serve as O-2-evolving catalysts in a system consisting of tris(2,2'-bipyridine)ruthenium(II) (Ru(bpy)(3)(2+)) and sodium persulfate (S2O82-) in an aqueous borate buffer solution at pH 8.0. Kinetics of O-2 evolution reveals that the higher cobalt nuclearity is not necessary to attain the highly active nature of the catalyst.
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