Journal
CHEMICAL COMMUNICATIONS
Volume 48, Issue 48, Pages 5980-5982Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c2cc32218h
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Funding
- MICINN [CTQ2007-60494/BQU, CTQ2010-15927]
- FPU
- CAM (AVANCAT)
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A diethynylxanthene unit is used to tether cyclometallated Pt(II) and Au(III) complexes in a geometry that favours interfacial interactions. This leads to protection from non-radiative decay pathways in the Au-2 dimer and to low-energy 'aggregate-like' emission in a closely related Pt-2 dimer, whilst rapid Au-to-Pt energy transfer occurs in the heterodimer.
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