4.7 Article

An inorganic propellane with central B-B bond

Journal

CHEMICAL COMMUNICATIONS
Volume 48, Issue 47, Pages 5886-5888

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c2cc32256k

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Funding

  1. Beilstein-Institut, Frankfurt/Main, Germany, within the research collaboration NanoBiC

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9,10-Dihydroanthracene-9,10-diyl-bridged B-2(NMe2)(2) readily adds [H2NMe2](+), HCl and F3CCOOH across its partial B=N double bond(s), thereby forming mono- or diadducts; treatment with 1-iso-propyl-2-mercaptoimidazole leads to a triply B-B-bridged propellane-like structure.

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