Journal
CHEMICAL COMMUNICATIONS
Volume 48, Issue 46, Pages 5736-5738Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c2cc31590d
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Funding
- National Natural Science Foundation [20971110, 91022013]
- Outstanding Talented Persons Foundation of Henan Province
- Natural Science Foundation of Henan Province Department of Education [2011A150015]
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[8 + 12]-metallamacrocycle-based 3D frameworks {[Cu-4(pbt)(2)(SO4)(2)(DMF)(2)(CH3OH)]center dot 7H(2)O center dot DMF}(n) (1) and [12]-macrocycle 3D {[Cu-2(pbt)(SO4)(DMSO)(CH3OH)(2)]center dot 5H(2)O center dot CH3OH}(n) (2) have been obtained. Both complexes display antiferromagnetic couplings and high catalytic activity in the oxidative coupling reaction of 1-ethynylbenzene and oxazolidin-2-one.
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