Journal
CHEMICAL COMMUNICATIONS
Volume 48, Issue 53, Pages 6714-6716Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c2cc32036c
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Funding
- Shanghai Science and Technology Committee [08DZ2270500]
- Program for Changjiang Scholars and Innovative Research Team in University [IRT1117]
- Shanghai Leading Academic Discipline Project [B108]
- National Basic Research Program of China [2009CB825300, 2010DFA41160]
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Several novel zwitterionic half-sandwich complexes and pseudocloso metallacarboranes based on 1,2-(PPh2)(2)-1,2-C2B10H10 were successfully prepared, and further study proved that some of them can activate H-2 to form the metal hydride complexes Cp*M(H)(7,8-(PPh2)(2)-7,8-C2B9H10) (M = Rh, Ir).
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