Journal
CHEMICAL COMMUNICATIONS
Volume 48, Issue 74, Pages 9230-9232Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c2cc32176a
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Funding
- EPSRC [EP/G036764/1]
- AstraZeneca
- GlaxoSmithKline
- Novartis
- Pfizer
- Syngenta
- University of Bristol
- Royal Society
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The expedient enantioselective synthesis of 5 bisabolane sesquiterpenes has been achieved using a common, one-pot lithiation-borylation reaction of secondary benzylic carbamates and either protodeboronation or oxidation to give the natural products in fewer than 5 steps, with high yield and >94 : 6 er.
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