Journal
CHEMICAL COMMUNICATIONS
Volume 48, Issue 46, Pages 5790-5792Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c2cc31624b
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- Konstanz Research School Chemical Biology
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Chelate stabilization of a titanium(IV)-salan alkoxide by ligand exchange with 2,6-pyridinedicarboxylic acid (dipic) resulted in heptacoordinate complex 3 which is not redox-active, stable on silica gel and has increased aqueous stability. 3 is highly toxic in HeLa S3 and Hep G2 and has enhanced antitumor efficacy in a mouse cervical-cancer model.
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