Journal
CHEMICAL COMMUNICATIONS
Volume 48, Issue 42, Pages 5065-5075Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c2cc17459f
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Funding
- Indiana University
- Jack K. Crandall Award
- Paget Organic Fellowship
- David A. Rothrock Award
- Raymond Siedle Fellowship
- National Science Foundation
- Department of Energy
- Dreyfus Foundation
- Royal Society of Chemistry
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Triazolophanes have recently surfaced as a new class of shape-persistent macrocycles that bind anions. Bearing only triazole- and phenyl-derived CH hydrogen bond donors, these receptors have shown extraordinary Cl binding strengths (> 10(6) M (1), CH2Cl2). The attributes of the triazolophane that are responsible are presented herein alongside recent literature accounts that have utilized similar strategies in new and exciting supramolecular systems. This review describes how triazolophanes leverage the structural pre-organization characteristic of spherands to take advantage of non-traditional hydrogen bonds originating from extrinsic CH donors.
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