4.7 Article

Dual-functional click-triazole: a metal chelator and immobilization linker for the construction of a heterogeneous palladium catalyst and its application for the aerobic oxidation of alcohols

Journal

CHEMICAL COMMUNICATIONS
Volume 48, Issue 24, Pages 2979-2981

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c2cc18023e

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Funding

  1. National Natural Science Foundation of China [20702051]
  2. Educational Commission of Zhejiang Province [Y 200907685]
  3. Key Scientific Technological Innovation Team of Zhejiang Province [2010R50018]

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A novel SBA-15 supported catalyst PdLn@SBA-15 containing a 2-pyridyl-1,2,3-triazole ligand framework was prepared via a click'' route, in which the click-triazole acted as both a stable linker and a good chelator. The catalyst was characterized and applied for the aerobic oxidation of alcohols, and the product was obtained in up to 98% yield.

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