Journal
CHEMICAL COMMUNICATIONS
Volume 48, Issue 47, Pages 5823-5825Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c2cc18090a
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Funding
- Nissan Chemical Industries, Ltd.
- World Premier International Research Center Initiative (WPI)
- MEXT, Japan [23245009]
- Global COE Program, 'Science for Future Molecular Systems
- JSPS
- Grants-in-Aid for Scientific Research [11J03551, 23245009] Funding Source: KAKEN
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A few Fe-salan dimer complexes serve as catalysts for aerobic oxidative coupling (AOC) of 2-naphthols, but some others do not. X-Ray and cyclic voltammetry studies of various Fe-salan complexes revealed that the absence or the presence of double hydrogen bonding in Fe-salan dimers, the oxidation potential of monomeric Fe-salan species and the location of the resulting radical cation are critical factors for the catalytic activity of iron-salan complexes for the AOC.
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