4.7 Article

Enhanced photocurrent production from thin films of Ru(II) metallopolymer/Dawson polyoxotungstate adducts under visible irradiation

Journal

CHEMICAL COMMUNICATIONS
Volume 48, Issue 30, Pages 3593-3595

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c2cc17431f

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Funding

  1. Science Foundation Ireland [10/IN.1/B3021]

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Thin films of polyoxometalates that are sensitized with a Ru(II) metallopolymer generate significant photocurrents in the presence of benzyl alcohol and visible light. Significantly, the photocurrent generated by the tungstate based adduct, alpha-[P2W18O62](6-), is approximately seven fold larger than that found for the Dawson polyoxomolybdate alpha-[S2Mo18O62](4-).

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