4.7 Article

Giving substance to the Losanitsch series

Journal

CHEMICAL COMMUNICATIONS
Volume 48, Issue 26, Pages 3158-3160

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c2cc17734j

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Funding

  1. Non-Equilibrium Energy Research Center which is an Energy Frontier Research Center
  2. US. Department of Energy, Offices of Basic Energy Sciences [DE-SC0000989]
  3. Swiss National Science Foundation
  4. KAIST in Korea [R31-2008-000-10055]

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A series of oligoparaxylene model compounds with two to six paraxylene units was synthesised and the resulting mixtures of atropisomers with one to five axes of chirality were analysed by dynamic H-1 NMR spectroscopy. The number of atropisomers was found to constitute part of the Losanitsch series.

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