Journal
CHEMICAL COMMUNICATIONS
Volume 48, Issue 66, Pages 8267-8269Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c2cc34052f
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- Deutsche Forschungsgemeinschaft [Me 2756/4]
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An efficient synthesis of diverse hetero-bis-metallated alkenes with conjugated and isolated olefin subunits is reported. Relying on those useful tin/boron reagents a convergent, palladium-catalyzed fragment coupling strategy has been developed as an elegant methodology to construct highly conjugated polyenes and stabilized olefinic analogues thereof. The utility of these reagents was further demonstrated in a concise and modular construction of extended polyene side chains of the potent polyketide antibiotic etnangien.
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