Journal
CHEMICAL COMMUNICATIONS
Volume 48, Issue 68, Pages 8562-8564Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c2cc33277a
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Funding
- Ministry of Education, Culture, Sports, Science and Technology, Japan. [22350017, 23685010]
- Grants-in-Aid for Scientific Research [23685010] Funding Source: KAKEN
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The synthesis and characterization of a stable 1,2-bis(ferrocenyl)diphosphene, wherein a P=P pi-bond connects two ferrocenyl units will be reported. This represents an unprecedented example for a d-pi electron system containing a heavier pnictogen pi-spacer group. Stabilization of the highly reactive P=P pi-bond was achieved by steric protection using two bulky ferrocenyl moieties.
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