4.7 Article

A phosphine-free Pd catalyst for the selective double carbonylation of aryl iodides

Journal

CHEMICAL COMMUNICATIONS
Volume 48, Issue 11, Pages 1695-1697

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c2cc17124d

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Funding

  1. Spanish Ministerio de Educacion y Ciencia [CTQ2008-01569-BQU, CTQ2010-15835, CSD2006-0003]

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The first phosphine-free Pd-catalysed double carbonylation of aryl iodides is reported as a general and practical method, giving excellent conversions and selectivities for a wide range of aryl iodides and amine nucleophiles under atmospheric CO pressure.

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