Journal
CHEMICAL COMMUNICATIONS
Volume 48, Issue 6, Pages 823-825Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c1cc16109a
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Funding
- SOLAR-H2
- Region Provence-Alpes-Cote d'Azur
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Ni-C in the O-2-tolerant hydrogenase I from Aquifex aeolicus binds a hydride weaker than that in O-2-sensitive hydrogenases. This is in line with the enhanced light-sensitivity of Ni-C, greater lability of the hydride complex and increased catalytic redox potentials relevant to bio-H-2 oxidation.
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