4.7 Article

Enhanced bistability by guest inclusion in Fe(II) spin crossover porous coordination polymers

Journal

CHEMICAL COMMUNICATIONS
Volume 48, Issue 39, Pages 4686-4688

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c2cc31048a

Keywords

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Funding

  1. Spanish (MICINN)
  2. FEDER [CTQ2010-18414, CTQ2011-23862-C02-01]
  3. Generalitat de Valencia and Catalunya [ACOMP2012/233, 2009SGR-1459]
  4. MEXT, Japan [22108512, 23245014]
  5. Conicyt-Chile
  6. Grants-in-Aid for Scientific Research [23245014, 22108512] Funding Source: KAKEN

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Inclusion of thiourea guest molecules in the tridimensional spin crossover porous coordination polymers {[Fe(pyrazine)[M(CN)(4)]} (M = Pd, Pt) leads to novel clathrates exhibiting unprecedented large thermal hysteresis loops of ca. 60 K wide centered near room temperature.

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