Journal
CHEMICAL COMMUNICATIONS
Volume 48, Issue 43, Pages 5277-5279Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c2cc31671d
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Funding
- DFG (Deutsche Forschungsgemeinschaft)
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The metal complexes [M{HB(hpp)}(2)(CO)(4)] (M= Cr, Mo or W) and [M(cod){HB(hpp)}(2)Cl] (M = Rh or Ir) of the doubly-base stabilized diborane(4) ligand [HB(hpp)](2) were fully characterized and their bonding nature was investigated in detail. While bonding in the group 6 complexes predominantly occurs through the hydrogen atoms, the metal-ligand interaction in the group 9 complexes can be regarded as an early stage oxidative addition of the boron-boron bond leading to diboryl compounds.
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