4.7 Article

A self-complexing and self-assembling pillar[5]arene

Journal

CHEMICAL COMMUNICATIONS
Volume 48, Issue 11, Pages 1647-1649

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c2cc16030g

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Funding

  1. World Class University (WCU) in Korea [R-31-2008-000-10055-0]
  2. National Science Foundation (NSF)/Engineering and Physical Sciences Research Council (EPSRC) [CHE-0924620]
  3. Chinese Scholarship Council
  4. NSF

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A monofunctionalised pillar[5]arene derivative carrying a viologen side chain which exhibits self-complexation in dilute dichloromethane solutions forms supramolecular daisy chain polymers and eventually organogels as its concentration is increased three-fold over the range from 0.1 to 100 mM.

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