4.7 Article

A single molecule magnet behaviour in a D3h symmetry Dy(III) complex involving a quinone-tetrathiafulvalene-quinone bridge

Journal

CHEMICAL COMMUNICATIONS
Volume 48, Issue 5, Pages 714-716

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c1cc16314k

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Funding

  1. CNRS
  2. Universite de Rennes 1, Region Bretagne, Rennes Metropole
  3. FEDER
  4. FSP [GK-P839]
  5. Russian Foundation for Basic Research [10-03-00788-a]
  6. Russian President Grant supporting scientific schools [NSh-7065.2010.3]

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A Dy(III)-based dinuclear complex was synthesised and characterised by X-ray diffraction on single crystal and magnetic investigations. Dynamic magnetic measurements reveal a single molecule magnet behaviour for 1 which can be described as two single-ion magnets in a D-3h local symmetry bridged by an acceptor-donor-acceptor ligand.

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