4.7 Article

Stepwise adsorption in a mesoporous metal-organic framework: experimental and computational analysis

Journal

CHEMICAL COMMUNICATIONS
Volume 48, Issue 27, Pages 3297-3299

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c2cc17168f

Keywords

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Funding

  1. U. S. Department of Energy [DE-FC36-07GO17033, DE-FC36-08GO18137]
  2. National Science Foundation [CBET-0930079]
  3. NSF/DOE [NSF/CHE-0822838]
  4. U. S. DOE, Office of Science, Office of Basic Energy Sciences [DE-AC02-06CH11357]

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Stepwise adsorption in a metal-organic framework with both micro- and meso-pores is caused by adsorbates first filling the micropores, then adsorbing along the mesopore walls, and finally filling the mesopores.

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