4.7 Article

A bifunctional catalyst for carbon dioxide fixation: cooperative double activation of epoxides for the synthesis of cyclic carbonates

Journal

CHEMICAL COMMUNICATIONS
Volume 48, Issue 37, Pages 4489-4491

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c2cc30591g

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Funding

  1. ENEOS Hydrogen Trust
  2. Japan Science and Technology Agency (JST)

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We have developed a very active bifunctional porphyrin catalyst showing a high turnover number (TON = 103 000) for the synthesis of cyclic carbonates from CO2 and epoxides under solvent-free conditions.

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