Journal
CHEMICAL COMMUNICATIONS
Volume 48, Issue 6, Pages 907-909Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c1cc15589j
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Funding
- Ministerio de Ciencia e Innovacion [MAT2008-05690/MAT]
- Gobierno Vasco [IT477-10]
- Universidad del Pais Vasco/Euskal Herriko Unibertsitatea [PIFA01/2007/021]
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The presence of butanoic acid excess in the reaction media employed for the synthesis of a MOF with formula [Cu-2(mu(3)-ade)(2)(mu(2)-OOC(CH2)(2)CH3)(2)](n) (ade: adeninate) leads to the formation of micelles that exert a template effect and provide a pronounced increase of its microporosity, doubling the intrinsic adsorption capacity of the pristine crystal network.
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