4.7 Article

Cyclodextrin-phosphane possessing a guest-tunable conformation for aqueous rhodium-catalyzed hydroformylation

Journal

CHEMICAL COMMUNICATIONS
Volume 48, Issue 5, Pages 753-755

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c1cc16326d

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Funding

  1. Centre National de la Recherche Scientifique (CNRS)
  2. Agence Nationale de la Recherche (ANR) [CP2D 2007 CATAQ]
  3. Ministere de l'Education et de la Recherche
  4. Reseau de Recherche (RDR2)

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The inclusion of a guest inside the cavity of a new water-soluble cyclodextrin-phosphane allows controlling the natural conformation of this ligand leading to an inversion of the regioselectivity during aqueous hydroformylation reaction.

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