Journal
CHEMICAL COMMUNICATIONS
Volume 48, Issue 92, Pages 11325-11327Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c2cc36171j
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A sterically shielded cationic NHC gold complex IPr**Au-BArF24 without solvent coordination has been prepared in situ in CH2Cl2-. The monovalent transition metal electrophile, a soft proton'', heterolytically activates the C-B bond of the weakly coordinating counterion tetrakis[3,5-bis(trifluoromethyl)phenyl]borate at room temperature.
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