Journal
CHEMICAL COMMUNICATIONS
Volume 48, Issue 78, Pages 9780-9782Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c2cc34451c
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Funding
- National Natural Science Foundation of China [21132002, 20972107]
- Priority Academic Program Development of Jiangsu Higher Education Institutions
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Polymerization of racemic lactide initiated by divalent ytterbium complexes supported by either dimethylamino-amino bis(phenolate) or methoxy-amino bis(phenolate) ligands proceeds rapidly at room temperature in a living fashion to give heterotactic polylactide with the racemic enchainment of monomer units P-r ranging from 0.97-0.99.
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