Journal
CHEMICAL COMMUNICATIONS
Volume 48, Issue 77, Pages 9610-9612Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c2cc35037h
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Funding
- National Science Foundation [CHE-0847262]
- Direct For Mathematical & Physical Scien [0847262] Funding Source: National Science Foundation
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A novel route to access trifluoromethylketones (TFMKs) from Weinreb amides is reported. This represents the first documented case of the Ruppert-Prakash reagent (TMS-CF3) reacting in a constructive manner with an amide and enables synthesis of TMFKs without risk of over-trifluoromethylation.
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