Journal
CHEMICAL COMMUNICATIONS
Volume 48, Issue 33, Pages 3996-3998Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c2cc30490b
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- Nanyang Technological University [RG 25/09]
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Free carbenes generated from alpha-diazo oxime ethers by photolysis undergo facile N-O insertion to afford 2-alkyl/aryloxy-2H-azirines in good to excellent yields. This method allowed for the development of a tandem reaction for pyrrole synthesis via 1,3-dipolar cycloaddition.
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