4.7 Article

A zinc porphyrin-based molecular probe for the determination of contamination in commercial acetonitrile

Journal

CHEMICAL COMMUNICATIONS
Volume 48, Issue 42, Pages 5109-5111

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c2cc31149f

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Funding

  1. National Research Foundation of Korea (NRF)
  2. Korea government (MEXT) [2011-0001126]
  3. Ministry of Education, Science and Technology, Korea

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A zinc porphyrin-based receptor containing four triazole groups at the ortho-position of each phenyl group (1) was utilized as a useful probe for the determination of contaminants in acetonitrile (MeCN). Through the simple observation of the absorption spectrum of 1 in MeCN, the cyanide contamination concentration could be directly determined.

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