4.7 Article

The formal potentials and electrode kinetics of the proton/hydrogen couple in various room temperature ionic liquids

Journal

CHEMICAL COMMUNICATIONS
Volume 48, Issue 45, Pages 5572-5574

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c2cc31402a

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Funding

  1. EPSRC [EP/H002413/1] Funding Source: UKRI
  2. Engineering and Physical Sciences Research Council [EP/H002413/1] Funding Source: researchfish

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The Hydrogen evolution reaction has been quantitatively investigated at a Pt electrode in series of room temperature ionic liquids vs. Ag/Ag+ redox couple. The measured formal potentials of the H2/H+ ( HNTf2) redox couple in each RTIL reveals a dependence on the nature of anion, suggesting significant interaction between proton and anion.

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