Journal
CHEMICAL COMMUNICATIONS
Volume 48, Issue 43, Pages 5352-5354Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c2cc30925d
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Funding
- National Natural Science Foundation of China
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Finely-tuned ruthenium-catalyzed highly chemoselective and enantioselective hydrogenation of gamma-halo-gamma,delta-unsaturated-beta-keto esters at the carbonyl group was achieved under neutral reaction conditions (ee up to 97%). Both olefin and alkenyl halogen moieties, which are labile under hydrogenation conditions, remained untouched during the reaction.
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