4.7 Article

1,3,5-Triphenylbenzene fluorophore as a selective Cu2+ sensor in aqueous media

Journal

CHEMICAL COMMUNICATIONS
Volume 48, Issue 2, Pages 293-295

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c1cc16148b

Keywords

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Funding

  1. National Nanotechnology Centre [P-11-00-00370, NN-B-22-FN9-10-52-06]
  2. Centre for Petroleum, Petrochemicals and Advanced Materials, Chulalongkorn University
  3. Thai Government [TKK2555, SP2]
  4. National Research University [AM 1006A]
  5. Chulalongkorn University

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Three water-soluble fluorophores are synthesized from 1,3,5-tris-(4'-iodophenyl)benzene. The compound with salicylate groups exhibits a selective fluorescent quenching by Cu2+ via a static quenching mechanism. The addition of Triton X-100 improves the quantum efficiency of the fluorophore as well as the detection limit for Cu2+ from 6.49 to 0.19 ppb.

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