4.7 Article

Slow magnetic relaxation in carbonato-bridged dinuclear lanthanide(III) complexes with 2,3-quinoxalinediolate ligands

Journal

CHEMICAL COMMUNICATIONS
Volume 48, Issue 62, Pages 7726-7728

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c2cc33674j

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Funding

  1. MICINN (Spain) [CTQ2010-15364, CSD2007-00010]
  2. Generalitat Valenciana (Spain) [PROMETEO/2009/108, ISIC/2012/002]
  3. ESRF (France) [HS3902, 25-01-783]
  4. MICINN

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The coordination chemistry of the 2,3-quinoxalinediolate ligand with different lanthanide(III) ions in basic media in air affords a new family of carbonato-bridged M-2(III) compounds (M = Pr, Gd and Dy), the Dy-2(III) analogue exhibiting slow magnetic relaxation behaviour typical of single-molecule magnets.

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