4.7 Article

Iridium-catalyzed reaction of enones with alcohols affording 1,3-diketones

Journal

CHEMICAL COMMUNICATIONS
Volume 48, Issue 53, Pages 6720-6722

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c2cc32787b

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Funding

  1. Ministry of Education, Culture, Sports, Science and Technology, Japan
  2. Kansai University
  3. Ministry of Education, Culture, Sports, Science and Technology
  4. Strategic Project to Support the Formation of Research Bases at Private Universities

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An iridium-catalyzed coupling reaction of alcohols with enones has been successfully developed providing access to 1,3-diketones with high selectivity in good yields. This reaction provides an atom-economical route to 1,3-diketones from readily available alcohols.

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