Journal
CHEMICAL COMMUNICATIONS
Volume 48, Issue 50, Pages 6295-6297Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c2cc32736h
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Funding
- NRF
- MEST [2012-0000912, 2012-0000098]
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The enantioselective synthesis of (-)-dysiherbaine (1) has been established with efficiency via a unique synthetic strategy involving the desymmetrization of 2-substituted glycerol to install a quaternary chiral carbon, which induces further stereochemistry in the bicyclic perhydrofuropyran through mercuriocyclization and epoxidation.
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