4.7 Article

Designed cyanide- and phenoxide-bridged FeIIIMnIII single-molecule magnet constructed by highly blocked paramagnetic precursors

Journal

CHEMICAL COMMUNICATIONS
Volume 48, Issue 59, Pages 7404-7406

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c2cc32503a

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Funding

  1. National Research Foundation of Korea
  2. Korean Government [2011-0003264]
  3. Priority Research Centers Program through the National Research Foundation of Korea (NRF)
  4. Ministry of Education, Science and Technology [NRF20110018396]
  5. PAL [2009-2063-05]

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A tetranuclear (Fe2Mn2III)-Mn-III compound was prepared using highly blocked precursors. The well-isolated molecular entity associated with appropriate magnetic anisotropy allows for single-molecule magnet behavior.

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