Journal
CHEMICAL COMMUNICATIONS
Volume 48, Issue 77, Pages 9628-9630Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c2cc34450e
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Funding
- National Science Council, Taiwan [NSC101-2113-M-033-008-MY3, NSC100-2632-M-033-001-MY3]
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New trimetallic magnesium complexes were synthesized for bifunctional catalysis. Complex 1 catalysed e-caprolactone polymerizations in not only a 'living' manner but also in an 'immortal' fashion. Additionally, tri-Mg 1 was active for the coupling of CO2 with cyclohexene oxide (CHO) on addition of n-Bu4NBr co-catalysts to give cis-cyclohexene carbonate under mild conditions.
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