Journal
CHEMICAL COMMUNICATIONS
Volume 48, Issue 32, Pages 3866-3868Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c2cc30801k
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- Grants-in-Aid for Scientific Research [21106001, 21106005] Funding Source: KAKEN
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Nickel(0) catalyzed [4+2] cycloaddition of electron-deficient dienes to alkynes and subsequent aromatization gave highly substituted arenes. This formal inverse electron-demand Diels-Alder cycloaddition is attributed to the formation of a seven-membered nickelacycle from a diene and an alkyne.
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